Ukraine readies for 'relentless defence' of Kyiv

In a video address posted on social media late Saturday night, President Volodymyr Zelensky said nevertheless the Russians did not have the strength or spirit to conquer Ukraine.

"The Russian invaders cannot conquer us. They do not have such strength. They do not have such spirit. They are holding only on violence. Only on terror. Only on weapons, which they have a lot," he said.

A convoy of humanitarian aid headed for Mariupol had been blocked at a Russian checkpoint, but it was hoped it could reach the city Sunday, Deputy Prime Minister Iryna Vereshchuk said.

The strategic port, in particular, is facing what Ukraine says is a "humanitarian catastrophe", with more than 1,500 civilians killed.

Attempts to evacuate hundreds of thousands of civilians have repeatedly failed. 

"Mariupol is still surrounded, that which they cannot have by war, (the Russians) want to have by hunger and despair. Since they cannot bring down the Ukrainian army, they target the population," a French military source said.

A top Russian officer described the situation in stark language.

"Unfortunately, the humanitarian situation in Ukraine is continuing to deteriorate rapidly, and in some cities, it has reached catastrophic proportions," said the head of the Russian National Defence Control Centre, Mikhail Mizintsev.

In his video address, Zelensky appealed for more aid.

"I keep reiterating to our allies and friends abroad; they have to keep doing more for our country, for Ukrainians and Ukraine. Because it is not only for Ukraine, but it is for all of Europe," he said.

- Glimmer of hope -

Intense efforts at diplomacy continued, with the leaders of France and Germany, Emmanuel Macron and Olaf Scholz, urging Russian counterpart Vladimir Putin during a three-way phone conversation on Saturday to end the deadly blockade, Paris said.

Facing growing international condemnation, Putin sought to turn the tables, slamming Kyiv for what he described as the "flagrant violation" of international humanitarian law and accusing Ukraine's army of executing dissenters and using civilians as hostages.

The French presidency denounced his accusations, made during the talks with Macron and Scholz, as "lies".

But in a small glimmer of hope, Zelensky said Saturday that Russia -- after appearing unbudging for days -- had adopted a "fundamentally different approach" in the latest talks to end the conflict. 

He told reporters he was "happy to have a signal from Russia" after Putin spoke of "some positive shifts" in a near-daily dialogue.

As Russia widens its bombardment, Zelensky's pleas for help have grown increasingly desperate.

Washington and its EU allies have sent funds and military aid to Ukraine and taken action against Russia's economy and oligarchs. A cultural and sporting boycott has further isolated Moscow.

In the Kyiv suburb of Irpin on Saturday, a Ukrainian soldier who gave his name only as Viktor showed off his British anti-tank missile system and the twisted remains of a Russian vehicle it destroyed.

"I want to say a big thank you to our British comrades helping us," he said.

As international sanctions against Moscow have steadily tightened, crippling Russia's economy, the country's space agency Roscosmos warned Saturday that the International Space Station could crash if Russian spacecraft serving it are affected.

But Washington on Friday added still more layers of sanctions, this time ending normal trade relations and announcing a ban on Russian vodka, seafood and diamonds.

And on Saturday, US President Joe Biden authorised up to $200 million in new weapons and other aid to Ukraine.

But he has ruled out direct action against nuclear-armed Russia, warning that it would lead to "World War III".

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- 'Cinders in his lungs' -

The situation in Mariupol remains "desperate", according to Doctors Without Borders, with no water or heating -- and food supplies dwindling.

"Hundreds of thousands of people... are for all intents and purposes besieged," Stephen Cornish, one of those heading the medical charity's Ukraine operation, told AFP.

He called sieges "a medieval practice" long outlawed.

In Kharkiv, in the east, doctors at a hospital described spending two days pumping ash from the stomach of an eight-year-old boy whose home was struck by a Russian missile.

"He still has cinders in his lungs," Dima Kasyanov's doctor told AFP.

Foreign combatants have entered the conflict on both sides, and on Friday, the Kremlin ramped up efforts to bring in reinforcements, particularly from Syria. 

In the Russian-held city of Melitopol, Zelensky said, 2,000 people protested against the kidnapping Friday of the mayor by Russian troops.

He called on Macron and Scholz to help secure Ivan Fedorov's release, which he said opened a "new stage of terror".